Gate effects in a hexagonal zinc-imidazolate-4-amide-5-imidate framework with flexible methoxy substituents and CO2 selectivity.
نویسندگان
چکیده
A new imidazolate-4-amide-5-imidate based MOF, IFP-7, is generated, having flexible methoxy groups, which act as molecular gates for guest molecules. This allows highly selective CO2 sorption over N2 and CH4 gases.
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ورودعنوان ژورنال:
- Chemical communications
دوره 49 69 شماره
صفحات -
تاریخ انتشار 2013